Surface Defects on Semicoherent and Incoherent NaCl-Type Carbides Dispersed in Hot-Rolled Ferritic Steel

Metallurgical and Materials Transactions A - The interface structure of semicoherent titanium carbide (TiC) nanoparticles and incoherent micron-sized TiC precipitates in Fe–C–Ti alloy...     

Management Levers for Product Platforms

Platforming has become an important means of cost-sharing among industrial products. However, many firms face systemic downward pressure on commonality, with the result that many platforms realize less commonality than intended. Past research has hypothesized that divergence is the result of conflicting tensions between product customization/optimization and cost control. This article investigates the control and incentive levers available to platform managers to shape the behavior of the organization when divergence opportunities arise. Management levers are drawn from a series of 12 industrial case studies, stemming from investigations of the causes of divergences. These management levers are categorized as technical levers, financial levers, and organizational levers. This article illustrates each of the management levers with examples from the case studies.     

Grafting of gold nanoparticles and nanorods on plasma-treated polymers by thiols

Grafting of gold nanoparticles and nanorods on the surface of polymers, modified by plasma discharge, is studied with the aim to create structures with potential applications in electronics or tissue engineering. Surfaces of polyethyleneterephthalate and polytetrafluoroethylene were modified by plasma discharge and subsequently, grafted with 2-mercaptoethanol, 4,4′-biphenyldithiol, and cysteamine. The thiols are expected to be fixed via one of –OH, –SH or –NH₂ groups to reactive places on the polymer surface created by the plasma treatment. “Free” –SH groups are allowed to interact (graft) with gold nanoparticles and nanorods. Gold nano-objects were characterized before grafting by transmission electron microscopy and UV–Vis spectroscopy. X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), and electrokinetic analysis (zeta potential determination) were used for the characterization of polymer surface at different modification phases. It was proved by FTIR and XPS measurements that the thiols were chemically bonded on the surface of the plasma-treated polymers, and they mediate subsequent grafting of the gold nano-objects. On the surfaces, modified polymers were indicated some objects by AFM, size of which was dramatically larger in comparison with that of original nanoparticles and nanorods. This result and the other results of UV–Vis spectroscopy indicate an aggregation of deposited gold nano-objects.     

ANN–supported control strategy for a solid oxide fuel cell working on demand for a public utility building

The idea of control strategy of SOFC operating to meet demand of a public utility building was presented. The strategy was formulated with the support of Artificial Neural Network. The network was used to predict the demand for electricity. The calculations were carried out on the example of a building of the Institute of Heat Engineering Warsaw University of Technology. The control strategy is influenced by various factors depending on changes in market conditions and operating characteristics of the cell. We can define different objective functions eg: working for own needs, for maximum profit and maximum service life. The article presents a simulation of SOFC operation for demand profile of the IHE building from the selected time period.     

Polyurethane/Polylactide-Based Electrospun Nonwovens as Carriers for Human Adipose-Derived Stromal Stem Cells and Chondrogenic Progenitor Cells

Articular cartilage dysfunctions are major cause of pain and disability and lead to serious health complications. Cell-based therapies are proposed as treatment methods for cartilage regeneration. In this study, we proposed polyurethane/poly(L-lactide-co-D, L-lactide)-based electrospun nonwovens as carriers for the delivery of human adipose-derived stromal stem cells. We found that 6:4 and 8:2 polyurethane/poly(L-lactide-co-D, L-lactide) initially enhance proliferative rate of human adipose-derived stromal stem cells, shorten their population doubling time, promote creation of functional chondrogenic nodules during chondrogenic differentiation, improve the collagen-2-to-collagen-1 protein ratio, and upregulate the expression of collagen-2 and aggrecan genes.     

Co-Production as a Driver of Urban Governance Transformation? The Case of the Oplan LIKAS Programme in Metro Manila,Philippines

Social movement-initiated co-production has been increasingly described as an approach that enables urban poor communities in the South to gain wider access to urban governance. However, with a predominant focus on project-level interventions, the case studies in which movements truly affect governance matters in a metro scale are rare. One of the examples involving such an achievement is the activism of civil society organisations and urban poor groups in Metro Manila, Philippines, which have succeeded to have a major impact on the housing and resettlement programme; the Oplan LIKAS. This article analyses how the civil society was able to gain such a position and the way it utilised it. The documentation of the challenges experienced by the civil society reflects the nature of co-productive engagement in the South and shows that it may easily reach its limits in an exclusionary governance setting.     

Effect of amine-terminated butadiene-acrylonitrile/clay combinations on the structure and properties of epoxy nanocomposites

The effect of the clay content and the method of its combination with amine-terminated butadiene-acrylonitrile (ATBN) on the structure and behavior of epoxy was studied. In the case of the simultaneous addition of both components, the increasing clay content had a very small effect on the size of the reaction-induced phase separation-formed particles at 5% rubber content due to predominant elimination of two major clay effects, i.e., the nucleation due to phase separation and the kinetics. As a result, both the time window between the onset of phase separation and vitrification and the viscosity at the cloud point did not change significantly. The minor change in the particle size/clay content dependences with different curing temperatures indicates that the balance between the two clay effects shifted. The corresponding study of the mechanical behavior indicated that the best balanced mechanical properties were obtained at certain clay/ATBN ratios, and thus, there was synergy between the components. Similar mechanical parameters were obtained for the application of both components in the form of ATBN/montmorillonite intercalate. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Nutrient and polyphenolic composition of industrial strawberry press cake

The objective of the present work was to determine the nutrient and polyphenolic composition of dried strawberry press cake (SPC), as well as that of its seedless fraction, termed exhausted strawberry flesh (ESF). The study materials were obtained over three consecutive years from an industrial facility manufacturing concentrated fruit juices. On average, SPC consists of 40 % seeds, 3.5 % sand, and about 55 % ESF. In the dry matter of SPC and ESF, the mean content of fat is 9.8 and 3.5 %, protein 17.3 and 20.4 %, and total polyphenols 3,449 and 5,410 mg/100 g, respectively. Both materials are rich in total dietary fiber, whose content amounts to 60 %. The predominant polyphenols in SPC and ESF are flavanols and ellagitannins, which collectively constitute over 95 % of the determined total polyphenol content. In ESF composition, of note is the high content of the strawberry ellagitannin, agrimoniin, which is approximately 1,000 mg/100 g DW (dry weight). SPC has the disadvantage of being highly contaminated with sand (3.4 %), which accumulates in ESF (5.6 %). However, as compared to SPC, ESF contains approximately 20 % more proteins and almost three times less fat. Based on our results, it appears that SPC may be considered a potential raw material for seed recovery. Moreover, dried strawberry press cake, and especially its seedless fraction (ESF), despite substantial contamination with sand, may be used as rich and widely available raw material for the extraction of proanthocyanidins and/or ellagitannins, and especially dimeric agrimoniin.     

Effects of ion irradiation in metallic glasses

Application of metallic glasses as structural materials has been limited by their poor ductility. To overcome brittle failure, nanocrystals are intentionally introduced to stabilize the glasses. In this study, we report on the application of ion irradiation to induce nanocrystalization in a Cu₅₀Zr₄₅Ti₅ (CZT) alloy. Transmission electron microcopy, microindentation and nanoindentation have been used to characterize the CZT alloy irradiated with 140 keV He ions at room temperature. Hardness enhancement was observed near the projected range of the He ions, coinciding with the formation of nanocrystals. Such microstructural changes, however, were not observed in the near surface region, where the electronic stopping process is dominant.